1-Octene, 1-decene and styrene have been hydroformylated using a CO 2-philic fluorous ligand associated with a rhodium catalyst. The effect of P/Rh molar ratio, partial pressure of CO/H2 and total pressure of carbon dioxide were studied. When 1-octene was used as the substrate, high conversion and selectivity in aldehydes were observed using low rhodium concentration and low P/Rh ratios. © 2006 Springer Science+Business Media, Inc.
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Pedrós, M. G., Masdeu-Bultó, A. M., Bayardon, J., & Sinou, D. (2006). Hydroformylation of alkenes with rhodium catalyst in supercritical carbon dioxide. Catalysis Letters, 107(3–4), 205–208. https://doi.org/10.1007/s10562-005-0005-7