The first synthesis of the whole antiostatin family is described by using an iron-mediated carbazole synthesis, regioselective nitration at C-4 and establishing 5-isobutyl-1-nitrobiuret as a reagent for introduction of the antiostatin B side chain at C-4. © 2009 The Royal Society of Chemistry.
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Knott, K. E., Auschill, S., Jäger, A., & Knölker, H. J. (2009). First total synthesis of the whole series of the antiostatins A and B. Chemical Communications, (12), 1467–1469. https://doi.org/10.1039/b821039j