Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station

Abstract

We present a modified retrieval strategy for solar absorption spectra recorded by the Karlsruhe Fourier Transform Infrared (FTIR) spectrometer, which is operational within the Total Carbon Column Observing Network (TCCON). In typical TCCON stations, the 3800–11g€¯000 cm−1 spectral region is measured on a single extended Indium Gallium Arsenide (InGaAs) detector. The Karlsruhe setup instead splits the spectrum across an Indium Antimonide (InSb) and InGaAs detector through the use of a dichroic beam splitter. This permits measurements further into the mid-infrared (MIR) that are of scientific interest, but are not considered TCCON measurements. This optical setup induces, however, larger variations in the continuum level of the solar spectra than the typical TCCON setup. Here we investigate the appropriate treatment of continuum-level variations in the retrieval strategy using the spectra recorded in Karlsruhe. The broad spectral windows used by TCCON require special attention with respect to residual curvature in the spectral fits. To accommodate the unique setup of Karlsruhe, higher-order discrete Legendre polynomial basis functions have been enabled in the TCCON retrieval code to fit the continuum. This improves spectral fits and air-mass dependencies for affected spectral windows. After fitting the continuum curvature, the Karlsruhe greenhouse gas records are in good agreement with other European TCCON data sets.