Eu3+ doped ZnAl layered double hydroxides as calibrationless, fluorescent sensors for carbonate

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Abstract

The photoluminescence properties (PL) of Eu3+ hosted in the hydroxide layers of layered double hydroxides (LDHs) enables calibrationless quantification of anions in the interlayers. The concept is demonstrated during the nitrate-to-carbonate ion exchange in Zn2+/Al3+/Eu3+ LDHs and can be implemented as a remote optical sensor to detect intrusion of anions such as Cl− or CO32−

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Morais, A. F., Silva, I. G. N., Ferreira, B. J., Teixeira, A. C., Sree, S. P., Terraschke, H., … Mustafa, D. (2023). Eu3+ doped ZnAl layered double hydroxides as calibrationless, fluorescent sensors for carbonate. Chemical Communications, 59(91), 13571–13574. https://doi.org/10.1039/d3cc03066k

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