Abstract
Heating of the compounds (RC5H4)Fe(CO) 2TePh (R = H (I) and Me (II)) in heptane afforded the dinuclear complexes [(RC5H4)Fe(CO)TePh]2 (III and IV, respectively). By oxidation with Fc+PF-6, these complexes were transformed into the paramagnetic cationic complexes [(RC 5H4)Fe(CO)TePh]2PF6 (Vand VI, respectively). Structures III-V and [(C5H5)Fe(CO)SPh] 2PF6 (VII) were characterized by X-ray diffraction. © Pleiades Publishing, Ltd., 2013.
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Shapovalov, S. S., Pasynskii, A. A., Skabitskii, I. V., Sidorenkov, A. S., Krishtop, T. A., & Minin, V. V. (2013). Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 39(12), 822–828. https://doi.org/10.1134/S1070328413120038
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