The Reaction of 1-Tetralones with Thallium Trinitrate Supported on Clay: Ring Contraction vs α-Oxidation

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Abstract

The reaction of a series of 1-tetralones with thallium trinitrate supported on Montmorillonite K-10 clay led to products of ring contraction (methyl indan-1-carboxylates) and/or α-oxidation (2-methoxy-1-tetralones), in variable yields.

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Ferraz, H. M. C., Silva, L. F., Aguilar, A. M., & Vieira, T. O. (2001). The Reaction of 1-Tetralones with Thallium Trinitrate Supported on Clay: Ring Contraction vs α-Oxidation. Journal of the Brazilian Chemical Society, 12(5), 680–684. https://doi.org/10.1590/S0103-50532001000500012

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