Skip to main content
Journal ArticleOPEN ACCESS

Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes

Chemical Communications (2021) 57(100) 13692-13695
DOI: 10.1039/d1cc05617d
9Citations
Citations of this article
18Readers
Mendeley users who have this article in their library.

Abstract

Heteroleptic zinc(i) complexes L1,2Zn-ZnCp* (L1= HC[C(CF3)NC6F5]21; L2= HC[C(Me)NDipp]2; Dipp = 2,6-i-Pr2C6H32) are synthesized by reactions of Cp*2Zn2with L1H and L2ZnH. 2 reacts witht-BuNCO to give unprecedented carbamate complex (4), while reactions with RN3gave bis-hexazene, triazenide, and trimeric azide complexes (5-7).

References Powered by Scopus

Catalytic reactions involving C<inf>1</inf> feedstocks: New high-activity Zn(II)- based catalysts for the alternating copolymerization of carbon dioxide and epoxides [22]

Journal of the American Chemical Society
546Citations
N/AReaders
Get full text

Decamethyldizincocene, a stable compound of Zn(I) with a Zn-Zn bond

Science
484Citations
N/AReaders
Get full text

Mechanism of the alternating copolymerization of epoxides and CO <inf>2</inf> using β-diiminate zinc catalysts: Evidence for a bimetallic epoxide enchainment

Journal of the American Chemical Society
480Citations
N/AReaders
Get full text
View more at Scopus

Cited by Powered by Scopus

Synthesis of low oxidation state zinc(i) complexes and their catalytic studies in the dehydroborylation of terminal alkynes

Dalton Transactions
11Citations
N/AReaders
Get full text

Dual Pathways in Catalytic Ammonia Oxidation by a Ruthenium Complex Bearing a Tetradentate Bipyridine-Bipyrazole Ligand: Isolation of a Diruthenium Intermediate with a μ-Hexazene Derivative

Journal of the American Chemical Society
10Citations
N/AReaders
Get full text

Reactions of Tetra(o-tolyl)diborane(4) with Organic Azides: Formation of Fluorescent Boron-Fused Hexazenes

Chemistry - A European Journal
8Citations
N/AReaders
Get full text
View more at Scopus

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Cite

CITATION STYLE

APA

Li, B., Huse, K., Wölper, C., & Schulz, S. (2021). Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes. Chemical Communications, 57(100), 13692–13695. https://doi.org/10.1039/d1cc05617d

Readers' Seniority

Tooltip

PhD / Post grad / Masters / Doc 2

67%

Professor / Associate Prof. 1

33%

Readers' Discipline

Tooltip

Chemistry 6

100%

Article Metrics

Tooltip
Social Media
Shares, Likes & Comments: 1

Save time finding and organizing research with Mendeley

Sign up for free