Abstract
A supramolecular strategy has been applied to construct two tetranuclear lanthanide complexes for investigating the magnetic properties of individual lanthanide ions. The LnIII complexes (Ln = Dy, Tb) display field-induced slow magnetization relaxation, typical of single-molecule magnet behavior. The four lanthanide ions in the molecules are well separated by distances of ca. 9 Å, and thus the slow magnetization relaxation should be assigned to single-ion magnet (SIM) behavior. Therefore, the present complexes are novel supramolecular aggregates of four isolated SIMs. © The Royal Society of Chemistry 2013.
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Wu, S. Q., Xie, Q. W., An, G. Y., Chen, X., Liu, C. M., Cui, A. L., & Kou, H. Z. (2013). Supramolecular lanthanide metallogrids exhibiting field-induced single-ion magnetic behavior. Dalton Transactions, 42(13), 4369–4372. https://doi.org/10.1039/c3dt50265a
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