Aldol reactions mediated by a tetrahedral boronate

Tobias Müller; Kristina Djanashvili; Isabel W.C.E. Arends; Ulf Hanefeld

Journal ArticleOPEN ACCESS

Aldol reactions mediated by a tetrahedral boronate

Müller T
Djanashvili K
Arends I
et al.

Chemical Communications (2013) 49(4) 361-363

DOI: 10.1039/c2cc37047f

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Abstract

The base is a key factor in aldol reactions in organic media, determining the selectivity. Here, we describe a tetrahedral phenylboronate salt as a mild non-nucleophilic base that is able to catalyse the aldol reaction and significantly decrease the formation of undesired elimination products. © 2012 The Royal Society of Chemistry.

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Müller, T., Djanashvili, K., Arends, I. W. C. E., & Hanefeld, U. (2013). Aldol reactions mediated by a tetrahedral boronate. Chemical Communications, 49(4), 361–363. https://doi.org/10.1039/c2cc37047f

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Aldol reactions mediated by a tetrahedral boronate

Abstract

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