Magnetic circular dichroism in X-ray fluorescence of Heusler alloys at threshold excitation

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Abstract

The results of fluorescence measurements of magnetic circular dichroism (MCD) in Mn L2,3 X-ray emission and absorption for Heusler alloys NiMnSb and Co2MnSb are presented. Very intense resonance Mn L3 emission is found at the Mn 2p3/2 threshold and attributed to a peculiarity of the threshold excitation in materials with a half-metallic character of the electronic structure. The excitation energy dependence of Mn L2,3 X-ray emission spectra (XES) was measured at beamline ID12B at the European Synchrotron Radiation Facility (ESRF, Grenoble) using 83% circularly polarized X-rays. A very large MCD effect found in XES is attributed to strong exchange splitting of spin-up and spin-down Mn 3d states. The anomalously high ratio of L2 emission intensity to L3 emission intensity is found.

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Yablonskikh, M. V., Grebennikov, V. I., Yarmoshenko, Y. M., Kurmaev, E. Z., Butorin, S. M., Duda, L. C., … Neumann, M. (2000). Magnetic circular dichroism in X-ray fluorescence of Heusler alloys at threshold excitation. Solid State Communications, 117(2), 79–82. https://doi.org/10.1016/S0038-1098(00)00415-4

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