Light hydrocarbon geochemistry of oils in the alpine Foreland basin: Impact of geothermal fluids on the petroleum system

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Abstract

Oil is produced in theAustrian sector of theAlpine Foreland Basin from Eocene andCenomanian reservoirs.Apart frompetroleum, the basin hosts a significant geothermal potential, which is based on the regional flow of meteoric water throughMalmian (Upper Jurassic) carbonate rocks. Oils are predominantly composed of n-alkanes, while some samples are progressively depleted in light aromatic components.The depletion in aromatic components relative to abundant n-alkanes is an effect of water washing.Waters coproduced with oils that are affected by water washing show a progressive reduction in salinity and depletion in 2H and 18O isotopes, indicating that the degree of water washing ismainly controlled by the inflow ofmeteoric water fromtheMalmian aquifer. In some fields with Cenomanian reservoir rocks, a hydraulic connectivity with the Malmian aquifer is evident. However, water washing is also recognized in Eocene reservoirs and in areas where the Malmian aquifer is missing. This shows that existing flow models for the regional Malmian aquifer have to be modified. Therefore, the results emphasize the importance of combining data from the petroleum and geothermal industry, which are often handled separately.

Figures

  • Figure 1: ((a) and (b)) Map of Europe with location of the study area in the Alpine Foreland Basin. (c) Distribution of oil fields together with the location of investigated samples. The B-B cross section is presented in Figure 8.
  • Figure 2: Time stratigraphic table of the Austrian part of the Alpine Foreland Basin; source rock and oil and gas occurrences are indicated (after [15–17]).
  • Figure 3: Thickness map of the Malmian horizon. Simplified thermal water system, regional water flow (modified from [8]), and location of oil fields are indicated. Inset presents location of map. Faults have been omitted to clarify the look of the map. The A-A cross section is presented in Figure 4.
  • Figure 4: Regional cross section from the recharge area in Lower Bavaria to the discharge area west of Linz (Upper Austria) (modified from [6]). Position of cross section is indicated in Figure 3 by a dashed line. Area marked by red rectangle is displayed in Figure 8.
  • Figure 5: Cross-plot of Na+ against Cl− dissolved in the water coproduced with oil. For comparison, data from this study are plotted together with industry and literature data. Deviation of the water from the seawater dilution line is probably caused by reservoir additives.
  • Figure 6: Cross-plot of the methylcyclohexane/toluene (Mch/T) ratio versus the cyclohexane/benzene (Ch/B) ratio. Ratios are calculated from chromatographic peak areas. Solubilities (mg/l at 20∘C) of different compounds in water are given in brackets. Because aromatic compounds are more soluble in water, water washing results in an increase in Mch/T and Ch/B ratios. The theoretical evaporation trend, assuming simple mixtures of two compounds, is indicated (vapor pressure at 20∘C for Mch: 48.3 hPa, Tol: 29.1 hPa, Ch: 104 hPa, B: 100 hPa after [18]). ∗Signature for kerogen type after Schaefer et al. [19]. Note that land plant-rich type III kerogen yields hydrocarbons with high contents of aromatic compounds resulting in very low Mch/T and Ch/B ratios. ∗∗Dotted line delineates typical Mch/T and Ch/B values from unaltered oils in the Rocky Mountain area [20], Gulf of Mexico (Pleistocene), California (Miocene), Louisiana (Lower Cretaceous [21]), North Slope (Alaska [22]), Mexican Gulf Coast Basin [23], North Central Sinai [24], and SW Barents Sea [25].
  • Figure 7: Cross-plots of the sum of two ratios between cycloalkanes and aromatic hydrocarbons versus (a) chlorine (Cl−) content in reservoir waters, (b) stable hydrogen isotope ratios of reservoir waters, and (c) stable oxygen isotope ratios of reservoir waters. For sample location, see Figure 1(c).
  • Figure 8: Simplified cross section of the oil field and location ofU1–U4 samples.Well U is used for reinjection of thermal water produced from Malmian (Upper Jurassic) horizon by a well located 3 km west of the section. Well UU is used as reinjector for reservoir brines coproduced with oil. Init. OWC: initial oil-water-contact at the beginning of oil production. Sec. OWC: secondary oil-water-contact estimated after 40 years of production. TVDSS: true vertical depth subsea.

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APA

Pytlak, Leis, A., Prochaska, W., Sachsenhofer, R. F., Gross, D., & Linzer, H. G. (2017). Light hydrocarbon geochemistry of oils in the alpine Foreland basin: Impact of geothermal fluids on the petroleum system. Geofluids, 2017. https://doi.org/10.1155/2017/7182959

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