High-efficiency Pd nanoparticles loaded porous organic polymers membrane catalytic reactors

Abstract

An innovative tactic to prepare porous organic polymer membranes was developedviainterfacial azo-coupling polymerization. The membranes possess plentiful anchoring sites for loading Pd nanoparticles, and served as a membrane reactor, which exhibits high-performance catalytic reduction with a flux of 27.3 t m−2day−1and good long-term stability due to almost zero Pd leaching.