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Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Chemical Communications (2022) 58(53) 7380-7383
DOI: 10.1039/d2cc02438a
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Abstract

The photoactivation mechanism of Os3(CO)12 at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os3(CO)11 with a ligand vacancy at the axial position.

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CITATION STYLE

APA

Ki, H., Kim, T. W., Moon, J., Kim, J., Lee, Y., Heo, J., … Ihee, H. (2022). Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography. Chemical Communications, 58(53), 7380–7383. https://doi.org/10.1039/d2cc02438a

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