Research on the spatial pattern distribution of soil selenium using machine learning methods integrating geographic proximity in complex terrain

Abstract

Purpose: Selenium is an essential trace element that offers various health benefits. However, its uneven distribution results in selenium deficiency in many regions. Here, we aimed to investigate the influence of environmental factors on soil Se concentration and predict the spatial distribution of selenium in topsoil. Methods: This study used 327 sample points to compare geostatistics and machine learning models for predicting soil selenium, considering five important conditioning factors including the parent material (geology), biology, topography, climate (MAP and ETA), and soil type using the R platform. We analyzed the relationship between these five factors and soil selenium through statistics and Pearson’s correlation coefficient. Results: Based on the R2, RMSE, CCC, and σZscore, the RFdc model demonstrated the best prediction efficacy, with R2 and RMSE values of 0.656 and 0.387. The results of spatial distribution predicted by the RFdc model and the relationship between environmental factors and soil selenium revealed that the parent rock significantly influenced the total selenium content. Soil type and land use factors exhibited significant correlations with selenium enrichment as well as topographic factors (slope and elevation) and climatic factors (precipitation). Selenium-rich (> 1.6 mg/kg) aggregation zones in Shitai County tended to be distributed in areas with the black rock system, early Paleozoic stratigraphy, and in forest areas with Alisol and Acrisold soils. Selenium-deficient areas (< 0.3 mg/kg) were mainly distributed in the central and eastern parts of the study area, which are plain areas along rivers and have Leptosols and Anthrosols soils. Conclusion: These findings can guide the development of the selenium-rich agricultural products industry in Shitai County as well as high-quality selenium-rich agricultural products for selenium-deficient areas in China. Meanwhile, effective agricultural measures can be taken to increase selenium concentrations through accurate identification of selenium-deficient areas.