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The catalytic activity of glass beads, silica gels and anion-exchange resins modified with metal-porphines in the oxidative reaction of NADH

Chemical and Pharmaceutical Bulletin (1999) 47(9) 1301-1304
DOI: 10.1248/cpb.47.1301
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Abstract

Silica gel and glass beads were modified using the acid chloride of metal-tetrakis(4-carboxyphenyl)porphine (M-TCPP) through a peptide bond, and an anion-exchange resin was modified with M-TCPP by electrostatic interaction and physical adsorption. The carriers modified with Co3+-TCPP proved to accelerate the following redox reaction: NADH + O2 carriers modified with Co-TCPP NADH+H2O2. The formation of hydrogen peroxide was confirmed by means of a colored reaction. The glass heads modified with Co3+-TCPP exhibited the strongest activity among the tested carriers, and were expected to be useful practically as a solid catalyst for the formation of hydrogen peroxide from NADH.

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APA

Iwado, A., Mifune, M., Harada, R., Oda, J., Motohashi, N., & Saito, Y. (1999). The catalytic activity of glass beads, silica gels and anion-exchange resins modified with metal-porphines in the oxidative reaction of NADH. Chemical and Pharmaceutical Bulletin, 47(9), 1301–1304. https://doi.org/10.1248/cpb.47.1301

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