Quantification of the enhanced effectiveness of NOx control from simultaneous reductions of VOC and NH3 for reducing air pollution in the Beijing-Tianjin-Hebei region, China

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Abstract

As one common precursor for both PM2.5 and O3 pollution, NOx gains great attention because its controls can be beneficial for reducing both PM2.5 and O3. However, the effectiveness of NOx controls for reducing PM2.5 and O3 are largely influenced by the ambient levels of NH3 and VOC, exhibiting strong nonlinearities characterized as NH3-limited/NH3-poor and NOx-/VOC-limited conditions, respectively. Quantification of such nonlinearities is a prerequisite for making suitable policy decisions but limitations of existing methods were recognized. In this study, a new method was developed by fitting multiple simulations of a chemical transport model (i.e., Community Multiscale Air Quality Modeling System, CMAQ) with a set of polynomial functions (denoted as pf-RSM) to quantify responses of ambient PM2.5 and O3 concentrations to changes in precursor emissions. The accuracy of the pf-RSM is carefully examined to meet the criteria of a mean normalized error within 2ĝ€% and a maximal normalized error within 10ĝ€% by using 40 training samples with marginal processing. An advantage of the pf-RSM method is that the nonlinearity in PM2.5 and O3 responses to precursor emission changes can be characterized by quantitative indicators, including (1) a peak ratio (denoted as PR) representing VOC-limited or NOx-limited conditions, (2) a suggested ratio of VOC reduction to NOx reduction to avoid increasing O3 under VOC-limited conditions, (3) a flex ratio (denoted as FR) representing NH3-poor or NH3-rich conditions, and (4) enhanced benefits in PM2.5 reductions from simultaneous reduction of NH3 with the same reduction rate of NOx. A case study in the Beijing-Tianjin-Hebei region suggested that most urban areas present strong VOC-limited conditions with a PR from 0.4 to 0.8 in July, implying that the NOx emission reduction rate needs to be greater than 20-60ĝ€% to pass the transition from VOC-limited to NOx-limited conditions. A simultaneous VOC control (the ratio of VOC reduction to NOx reduction is about 0.5-1.2) can avoid increasing O3 during the transition. For PM2.5, most urban areas present strong NH3-rich conditions with a PR from 0.75 to 0.95, implying that NH3 is sufficiently abundant to neutralize extra nitric acid produced by an additional 5-35ĝ€% of NOx emissions. Enhanced benefits in PM2.5 reductions from simultaneous reduction of NH3 were estimated to be 0.04-0.15ĝ€μgĝ€mĝ'3 PM2.5 per 1ĝ€% reduction of NH3 along with NOx, with greater benefits in July when the NH3-rich conditions are not as strong as in January. Thus, the newly developed pf-RSM model has successfully quantified the enhanced effectiveness of NOx control, and simultaneous reduction of VOC and NH3 with NOx can assure the control effectiveness of PM2.5 and O3.

Figures

  • Table 2. Out of sample dataset for validation
  • Table 3. Performance of PM2.5 and O3 prediction using pf-RSM with different training samples
  • Table 4. Estimation of indicators that representing the nonlinear control effectiveness for reducing PM2.5 and O3 in BeijingTianjin-Hebei region
  • Figure 1. Schematic plot of comparison between traditional RSM (regression-based) and RSM with polynomial function (denoted as “pf-RSM”, fitting-based)
  • Figure 2. Flow scheme of pf-RSM development
  • Figure 3. Fitting the PM2.5 responsive function with a polynomial of a single indeterminate plots
  • Figure 5. Definition of Peak Ratio (PR) and suggested VOC/NOx Ratio (VNr) basing on the 2-D isopleths of O3 sensitivity to NOx and VOC emission changes (an example in Beijing in July)
  • Figure 6. Definition of Flex Ratio (FR) and extra benefit from simultaneous reduction of NH3 basing on the 2-D isopleths of PM2.5 sensitivity to NOx and NH3 emission changes (an example in Beijing in July)

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Xing, J., Ding, D., Wang, S., Zhao, B., Jang, C., Wu, W., … Hao, J. (2018). Quantification of the enhanced effectiveness of NOx control from simultaneous reductions of VOC and NH3 for reducing air pollution in the Beijing-Tianjin-Hebei region, China. Atmospheric Chemistry and Physics, 18(11), 7799–7814. https://doi.org/10.5194/acp-18-7799-2018

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