Synthesis and characteristic stereostructure of a biphenanthryl ether

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Abstract

A biphenanthryl ether with substituents in the bay regions was efficiently synthesized for the first time. The unique stereostructure of 1 was clarified. Its twisted conformation and optical behavior as well as its characteristic supramolecular helical structure, which is constructed through a C-H⋯F hydrogen bonding network in the solid state, are discussed. © 2008 Elsevier Ltd. All rights reserved.

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Koizumi, Y., Suzuki, S., Takeda, K., Murahashi, K., Horikawa, M., Katagiri, K., … Kan, T. (2008). Synthesis and characteristic stereostructure of a biphenanthryl ether. Tetrahedron Asymmetry, 19(12), 1407–1410. https://doi.org/10.1016/j.tetasy.2008.05.001

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