Light scattering study of acoustic phonon modes and central peaks in Pb [(Mg13 Nb23) 0.45 Ti0.55] O3 single crystals

Abstract

The dynamic polar nanoregions (PNRs) which form below the Burns temperature and determine the unique properties of relaxor ferroelectrics were predicted [Tinte, Phys. Rev. Lett. 97, 137601 (2006)] to be pinned to the quenched chemically ordered regions (CORs) usually observed in lead-containing relaxors. In Pb [(Mg13 Nb23) 0.45 Ti0.55] O3 crystal where CORs are known to be absent, we have found the phenomena typically related to the relaxation of dynamic PNRs, namely, the significant Brillouin quasielastic scattering, the softening of the longitudinal acoustic mode, and the deviation from the Curie-Weiss law above the Curie point. This implies that PNRs may appear in crystals without CORs. © 2007 American Institute of Physics.