Improving the Performance of PVDF/PVDF- g-PEGMA Ultrafiltration Membranes by Partial Solvent Substitution with Green Solvent Dimethyl Sulfoxide during Fabrication

Abstract

Traditional organic solvents used in membrane manufacturing, such as dimethylformamide and tetrahydrofuran, are generally very hazardous and harmful to the environment and human health. Their total or partial substitution with green solvent dimethyl sulfoxide (DMSO) is proposed to fabricate membranes composed of poly(vinylidene fluoride) (PVDF) blended with PVDF-graft-poly(ethylene glycol) methyl ether methacrylate (PEGMA), with the purpose to accomplish a greener chemical process and enhance the membrane performance. Various organic solvent compositions were first investigated using the Hansen solubility theory, and the best mixture was thus applied experimentally. The membrane prepared by a ratio of N,N-dimethylacetamide/DMSO = 7:3 outperformed the membranes prepared by other solvent mixtures. This membrane showed high wetting behavior with the water contact angle declining from 71 to 7° in 18 s and a pure water flux reaching values larger than 700 L m-2 h-1 under 0.07 MPa applied hydraulic pressure. The membrane rejected sodium alginate at a rate of 87%, and nearly complete flux recovery was achieved following fouling and physical cleaning. The introduction of green chemistry concepts to PVDF/PVDF-g-PEGMA blended membranes is a step forward in the goal to increase the sustainability of membrane production.