Abstract
(Chemical Equation Presented) Two metals in a pod: The combination of Pd and La with a dinucleating Schiff base was developed for anti selectivity in the catalytic asymmetric nitroaldol reaction (see scheme). Short syntheses of β-adrenoceptor agonists by using the heterobimetallic catalyst are presented. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Handa, S., Nagawa, K., Sohtome, Y., Matsunaga, S., & Shibasaki, M. (2008). A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of β-adrenoceptor agonists. Angewandte Chemie - International Edition, 47(17), 3230–3233. https://doi.org/10.1002/anie.200705617
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