Functionalized-carbon nanotube supported electrocatalysts and buckypaper-based biocathodes for glucose fuel cell applications

Abstract

The preparation and testing for electrocatalytic activity of functionalized carbon nanotube (f-CNT) supported Pt and Au-Pt nanoparticles (NPs), and bilirubin oxidase (BOD), are reported. These materials were utilized as oxygen reduction reaction (ORR) cathode electrocatalysts in a phosphate buffer solution (0.2 M, pH 7.4) at 25 °C, in the absence and presence of glucose. Carbon monoxide (CO) stripping voltammetry was applied to determine the electrochemically active surface area (ESA). The ORR performance of the Pt/f-CNTs catalyst was high (specific activity of 80.9 μA cm Pt-2 at 0.8 V vs. RHE) with an open circuit potential within ca. 10 mV of that delivered by state-of-the-art carbon supported platinum catalyst and exhibited better glucose tolerance. The f-CNT support favors a higher electrocatalytic activity of BOD for the ORR than a commercially available carbon black (Vulcan XC-72R). These results demonstrate that f-CNTs are a promising electrocatalyst supporting substrate for biofuel cell applications. © 2011 Elsevier Ltd. All rights reserved.